[C6H5CH2NH2CH2P(cyclo-CH2N(CH2C6H5)CH2N(CH2C6H5)CH2))]SbF6 | 1130651-88-5

• 英文名称: [C6H5CH2NH2CH2P(cyclo-CH2N(CH2C6H5)CH2N(CH2C6H5)CH2))]SbF6
• 英文别名: [P(CH2NH2CH2C6H5)(CH2N(CH2C6H5)CH2N(CH2C6H5)CH2]SbF6
• CAS: 1130651-88-5
• 化学式: C₂₅H₃₁N₃P*F₆Sb
• 分子量: 640.255
• InChiKey: WRCKXIQWCVMGLG-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(acetonitrile)dichloroplatinum(II) 、 [C6H5CH2NH2CH2P(cyclo-CH2N(CH2C6H5)CH2N(CH2C6H5)CH2))]SbF6 以 CH₂Cl₂ 为溶剂， 以82%的产率得到[PtCl2(C6H5CH2NH2CH2P(cyclo-CH2N(CH2C6H5)CH2N(CH2C6H5)CH2))2](SbF6)2
  参考文献：
  名称：

  Unusual Metal-Coordinated Zwitterionic P−C−N−C−N−C Phosphido Adducts

  摘要：

  Rare examples of homodinuclear zwitterionic Pd-II and Pt-II complexes with bridging, two-coordinate P{cyclo-CH2N(R)CHN-(R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N-C distances and enlarged N-C-N bond angles support electron delocalization in the central N-C-N backbone.

  DOI：

  10.1021/ic1002308

文献信息

• Intramolecular Hydrogen-Bonded Tertiary Phosphines as 1,3,5-Triaza-7-phosphaadamantane (PTA) Analogues
  作者：Allen T. Ekubo、Mark R. J. Elsegood、Andrew J. Lake、Martin B. Smith

  DOI：10.1021/ic801709z

  日期：2009.3.16

  New cationic trialkylphosphines [P(CH2NH2R)CH2N(R)CH2N(R)CH2}](+) (R = C6H5CH2, a; 4-FC6H4CH2, b), as their Cl- (1a, 1b), SbF6- (2a, 2b), and PF6- (3a, 3b) salts, are described. The phosphine framework is conformationally locked, in the solid state, through pairs of intramolecular N-H center dot center dot center dot N hydrogen bonds which are maintained in the Ru-II and Rh-III complexes 4 and 5. Phosphines 1a-3b can be considered as charged variants of the well-known PTA ligand.