CuCl(2-oxyacetophenone-N(4)-phenyl semicarbazone) | 939017-60-4

• 英文名称: CuCl(2-oxyacetophenone-N(4)-phenyl semicarbazone)
• CAS: 939017-60-4
• 化学式: C₁₅H₁₄ClCuN₃O₂
• 分子量: 367.294
• InChiKey: LVFGZSVPOQOYCR-HSZLIDMQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-hydroxyacetophenone N(4)-phenyl semicarbazone 、 copper dichloride 以 甲醇 为溶剂， 生成 CuCl(2-oxyacetophenone-N(4)-phenyl semicarbazone)
  参考文献：
  名称：

  Synthesis, spectral characterization and crystal structure of copper(II) complexes of 2-hydroxyacetophenone-N(4)-phenyl semicarbazone

  摘要：

  Six new copper(11) complexes of 2-hydroxyacetophenone-N(4)-phenyl semicarbazone have been synthesized and physico-chemically characterized. The tridentate character of the semicarbazone is inferred from IR spectra. Based on EPR studies, the spin Hamiltonian and bonding parameters have been calculated. The g values, calculated for all the complexes in frozen DMF, indicate the presence of the unpaired electron in the d(x2-y2) orbital. The metal-ligand bonding parameters evaluated showed strong in-plane U and in-plane it-bonding. The structure of the compound, CuLphen has been resolved using single crystal X-ray diffraction studies. The crystal structure revealed a monoclinic lattice with space group symmetry P2(1)/c. The compound adopts a distorted square pyramidal geometry with a N2O2 core as the base. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.11.035