Zn2[7,16-dihydroxy-6',13'-dimethyl-1,4,10,13-tetraaza-tetrabenzo[2,3-a;6,7,8-f,a;11,12-a;15,16,17-f,a]cyclooctadeca-2,4,6,9,11,13 | 1187785-27-8

• 英文名称: Zn2[7,16-dihydroxy-6',13'-dimethyl-1,4,10,13-tetraaza-tetrabenzo[2,3-a;6,7,8-f,a;11,12-a;15,16,17-f,a]cyclooctadeca-2,4,6,9,11,13
• CAS: 1187785-27-8
• 化学式: C₃₀H₂₂Cl₂N₄O₂Zn₂*H₂O
• 分子量: 690.232
• InChiKey: WDBKKXGGHVPODY-MFVSJRFOSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二甲酰-4-甲基苯酚 、 邻苯二胺 、 zinc(II) chloride 以 neat (no solvent, solid phase) 为溶剂， 生成 Zn2[7,16-dihydroxy-6',13'-dimethyl-1,4,10,13-tetraaza-tetrabenzo[2,3-a;6,7,8-f,a;11,12-a;15,16,17-f,a]cyclooctadeca-2,4,6,9,11,13
  参考文献：
  名称：

  Optical properties of binuclear zinc (II) macrocyclic complexes derived from 4-methyl-2,6-diformylphenol and 1,2-diaminobenzene

  摘要：

  In this work, we present the synthesis and optical study of the binuclear zinc(II) macrocyclic complexes, derived from 4-methyl-2,6-diformyl phenol and 1,2-diaminobenzene (H2L). Two zinc macrocyclic complexes with different anions were prepared and characterized: [Zn2LCl2]center dot H2O (1) and [Zn2L](NO3)(2) (2).The complexes are emissive, both in the solid state and in solution at room temperature. Spectroscopic properties of the macrocyclic complexes were investigated using stationary and time resolved methods in solutions of dimethylsulfoxide (DMSO), and in solid state. DMSO solutions show two emission bands centered at 480 and 521 nm for complex (1), and at 527 nm with a shoulder at 480 nm for (2). The emission spectra of these compounds in solid state show a red shifted band, presenting the maxima at 565 nm for (1) and 575 nm for (2). The emission lifetimes for these compounds are very short, viz. 650 and 480 ps for macrocycles (1) and (2), respectively. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.04.027