| 405316-07-6

• CAS: 405316-07-6
• 化学式: C₂₄H₄₂IrN₂*F₆P
• 分子量: 695.795
• InChiKey: UGSALWQQXOFETB-KJSXAQCBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 sodium cyanoborohydride 以 乙醇 、 水 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Qualitatively Different Reactivities of Hydride Reagents toward [(α-diimine)(η⁵-C₅Me₅)ClIr]⁺ Cations:  Substitution, Electron Transfer (Reduction), or Stepwise Hydrogenation

  摘要：

  Whereas complex cations [(alpha-diimine)(eta(5)-C-5-Me-5)ClIr](+) with 2,2'-bipyridine and related aromatic ligands show only the expected Cl/H exchange on reaction with borohydrides, the systems [(RN=CHCH=NR)(eta(5)-C5Me5)ClIr](+) undergo reduction to the enediamido(2-)-iridium,(III) species [(RNCH=CHNR)(eta(5)-C-5-Me-5)Ir], even in protic media, if R is an axially shielding 2,6-dialkylphenyl group. In protic media the complex ion with R = cyclohexyl undergoes Cl/H exchange and stepwise hydrogenation of the a-diimine ligand via [(RHNCH2CH=NR)(eta(5)-C5Me5)HIr](PF6) to the structurally characterized compound [(RHNCH2CH2NHR)(eta(5)-C5Me6)HIr][BH3(CN)].

  DOI：

  10.1021/om010529k