[ruthenium(II)(2,2':6',2''-terpyridine)(2,2'-bipyrimidine)(chloride)](1+) | 433921-79-0

• 英文名称: [ruthenium(II)(2,2':6',2''-terpyridine)(2,2'-bipyrimidine)(chloride)](1+)
• 英文别名: [(2,2'-bipyrimidine)Ru(2,2':6',2''-terpyridine)Cl](1+)；[(2,2':6',2''-terpyridine)RuCl(2,2'-bipyrimidine)](1+)；[Ru(2,2':6,2''-terpyridine)(2,2'-bipyrimidine)Cl](1+)；[(2,2':6',6''-terpyridine)RuCl(bipyrimidine)]；[(tpy)RuCl(bpm)](1+)；[Ru(tpy)(bpm)Cl](1+)
• CAS: 433921-79-0
• 化学式: C₂₃H₁₇ClN₇Ru
• 分子量: 527.958
• InChiKey: PXFKGVCSVAYKQM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [ruthenium(II)(2,2':6',2''-terpyridine)(2,2'-bipyrimidine)(chloride)](1+) 、 水 在 silver nitrate 作用下， 以 甲醇 、 水 为溶剂， 生成 [Ru(2,2'-bipyrimidine)(2,2′:6′,2″-terpyridine)(H₂O)](2+)
  参考文献：
  名称：

  One Site is Enough. Catalytic Water Oxidation by [Ru(tpy)(bpm)(OH₂)]²⁺ and [Ru(tpy)(bpz)(OH₂)]²⁺

  摘要：

  Water oxidation is a key reaction in natural photosynthesis and in many schemes for artificial photosynthesis. Although metal complexes capable of oxidizing water based on Ru, Mn, and Ir are known, a significant question is whether or not dimeric or higher order structures are required for water oxidation. We report here single-site catalytic water oxidation by the monomeric complexes [Ru(tpy)(bpm)(OH2)](2+) and [Ru(tpy)(bpz)(OH2)](2+) (tpy is 2,2':6',2 ''-terpyridine; bpm is 2,2'-bipyrimidine; bpz is 2,2'-bipyrazine) by a well-defined mechanism involving Ru-v square O.

  DOI：

  10.1021/ja8059649

文献信息

• Catalytic and Surface-Electrocatalytic Water Oxidation by Redox Mediator-Catalyst Assemblies
  作者：Javier J. Concepcion、Jonah W. Jurss、Paul G. Hoertz、Thomas J. Meyer

  DOI：10.1002/anie.200901279

  日期：2009.12.7

  All‐in‐one assemblies containing single‐site water oxidation catalysts (red and blue) and redox mediators (green and blue) act as stable, robust catalysts toward water oxidation, both in solution and anchored to metal oxide surfaces by phosphonate linkers on the mediator. More than 28 000 turnovers have been achieved with >95 % Faradaic efficiency for oxygen production without reduced catalytic activity

  包含单一位点水氧化催化剂（红色和蓝色）和氧化还原介体（绿色和蓝色）的多合一组件在溶液中起稳定，强大的抗水氧化作用，无论是在溶液中还是通过膦酸酯连接子固定在金属氧化物表面上调解员。在不降低催化活性的情况下，以> 95％的法拉第效率生产氧气已经实现了28000多个营业额。