[palladium(II)chloride(pyridine-2,6-di(C(CH3)NC6H3(CH3)2))](palladium(II)trichloride) | 1245796-63-7

• 英文名称: [palladium(II)chloride(pyridine-2,6-di(C(CH3)NC6H3(CH3)2))](palladium(II)trichloride)
• CAS: 1245796-63-7
• 化学式: C₂₅H₂₇ClN₃Pd*Cl₃Pd
• 分子量: 724.161
• InChiKey: NSQVAXWFERNNTF-HURGSMQESA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  pyridine-2,6-di(C(CH3)NC6H3(CH3)2) 、 palladium dichloride 以 ethanol 为溶剂， 以93%的产率得到[palladium(II)chloride(pyridine-2,6-di(C(CH3)NC6H3(CH3)2))](palladium(II)trichloride)
  参考文献：
  名称：

  Palladium(II) Complexes Containing 2,6-Bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions

  摘要：

  A series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change S*, enthalpy change H#, and Gibbs free energy change G# of the thermal decomposition were calculated by means of several methods based on the single heating rate.

  DOI：

  10.1080/15533174.2010.486822