[PtCl(2-hydroxynicotinate)(2,2'-bipyridine) | 503811-71-0

• 英文名称: [PtCl(2-hydroxynicotinate)(2,2'-bipyridine)
• CAS: 503811-71-0
• 化学式: C₁₆H₁₂ClN₃O₃Pt
• 分子量: 524.823
• InChiKey: NWLPVWYVKJSRML-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-羟基烟酸 、 (2,2-联吡啶)二氯铂(II) 在 triethylamine 作用下， 以 甲醇 、 乙醇 为溶剂， 以87%的产率得到[PtCl(2-hydroxynicotinate)(2,2'-bipyridine)
  参考文献：
  名称：

  Coordination modes of 2-hydroxynicotinic acid in second- and third-row transition metal complexes

  摘要：

  The new Pd(II), Pt(II), Re(V), Mo(VI) and W(VI) complexes of 2-hydroxynicotinic acid (H(2)nicO), trans-[PdCl(HnicO)(PPh3)(2)].0.75CH(3)CN (1), K[PdCl(HnicO)(2)].H2O (2), [Pd(HnicO)(2)(bipy)] (3), cis-[PtCl(HnicO)(PPh3)(2)].0.75CH(3)OH.0.5H(2)O (4), [PtCl(HnicO)(bipy)] (5), cis-[ReOI2(HnicO)(PPh3)] (6), Na-2[Mo2O6(HnicO)(2)].5H(2)O (7), Na-2[Mo4O12(HnicO)(2)].2H(2)O (8) and Na-2[W2O6(HnicO)(2)].5H(2)O (9) have been prepared. The crystal structures of I and 4, were determined by X-ray diffraction and show the HnicO(-) ligand coordinated to palladium or platinum through the nitrogen atom only. Infrared, Raman, H-1 and C-13{H-1} NMR spectroscopic data for the complexes are presented and are in agreement with the crystallographic results. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01283-4