[Fe(CO)2(C5Me4CH2)]Si(H)C5Me5 | 1227796-92-0

• 英文名称: [Fe(CO)2(C5Me4CH2)]Si(H)C5Me5
• 英文别名: [Fe(carbonyl)2(C5Me4CH2)]Si(H)Cp(*)
• CAS: 1227796-92-0
• 化学式: C₂₂H₃₀FeO₂Si
• 分子量: 410.411
• InChiKey: LFETXQVRPWHEPY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(η5-pentamethylcyclopentadienyl)dicarbonylferrio](η3-pentamethylcyclopentadienyl)silicon 以 neat (no solvent, solid phase) 为溶剂， 以99%的产率得到[Fe(CO)2(C5Me4CH2)]Si(H)C5Me5
  参考文献：
  名称：

  Synthesis and Characterization of the Ferrio-Substituted Silicon(II) Compound Me₅C₅(CO)₂FeSiC₅Me₅

  摘要：

  Reaction of the (pentamethylcyclopentadienyl)silicon cation with the (pentamethylcyclopentadienyl)dicarbonylferrate anion leads to the formation of the crystalline, thermolabile silicon(II) compound [(eta(5)-pentamethylcyclopentadienyl)dicarbonylferrio](eta(3)-pentamethylcyclopentadienyl)silicon. The singlet triplet energy difference Delta E-ST is calculated to be 25.4 kcal/mol.

  DOI：

  10.1021/om100366f