(hexacarbonyl)(μ-tetraphenylimidodiselenophosphinato-κ2Se,Se')(μ-tetraphenylimidodithiophosphinato-κ2-S,S')dirhenium | 1258691-78-9

• 英文名称: (hexacarbonyl)(μ-tetraphenylimidodiselenophosphinato-κ2Se,Se')(μ-tetraphenylimidodithiophosphinato-κ2-S,S')dirhenium
• 英文别名: Re2(CO)6[μ-Ph2P(Se)NP(Se)Ph2-κ2-Se,Se'][μ-Ph2P(S)NP(S)Ph2-κ2-S,S']
• CAS: 1258691-78-9
• 化学式: C₅₄H₄₀N₂O₆P₄Re₂S₂Se₂
• 分子量: 1531.28
• InChiKey: IGCGDUUSVWTGIR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (μ-bromido)(hexacarbonyl)(μ-tetraphenylimidodithiophosphinato-κ2S,S')dirhenium 、 potassium bis(diphenylselenophosphoryl)amide 以 甲苯 为溶剂， 以75%的产率得到(hexacarbonyl)(μ-tetraphenylimidodiselenophosphinato-κ2Se,Se')(μ-tetraphenylimidodithiophosphinato-κ2-S,S')dirhenium
  参考文献：
  名称：

  Formation of carbonylrhenium cryptates with alkali metal cations: Coordination chemistry studies of [Ph2P(E)NP(E)Ph2]−, E=O, S, Se towards ReBr(CO)5

  摘要：

  Reaction of ReBr(CO)(5) with Li[Ph2P(O)NP(O)Ph-2] afforded the cryptate Li[Re-2(CO)(6)]{mu-Ph2P(O)NP(O)Ph-2-kappa O-2,O'}(3)]; whereas K[Ph2P(O)NP(O)Ph-2] reacted with ReBr(CO)(5) to give K[Re-2(CO)(6){mu-Ph2P(O)NP(O)Ph-2-kappa O-2,O'}{Ph2P(O)NP(O)Ph-2-kappa O-2,O'}(2)]. Other chalcogen ligands' salts M[Ph2P(E)NP(E)Ph-2], E = Se and S. M = K and Li gave dirhenium carbonyls with bromido and Ph2P(E)NP(E)Ph-2, E = Se or S bridges upon reaction with ReBr(CO)(5). (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.011