2-methoxycarbonyl-6-(1-(2,6-dibromo-4-methylphenylimino)ethyl)pyridyl palladium dichloride | 916484-91-8

• 英文名称: 2-methoxycarbonyl-6-(1-(2,6-dibromo-4-methylphenylimino)ethyl)pyridyl palladium dichloride
• CAS: 916484-91-8
• 化学式: C₁₆H₁₄Br₂Cl₂N₂O₂Pd
• 分子量: 603.433
• InChiKey: QPCYYENRFQTDTB-DWZOPUQCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 2-methoxycarbonyl-6-(1-(2,6-dibromo-4-methylphenylimino)ethyl)pyridine 以 二氯甲烷 为溶剂， 以90%的产率得到2-methoxycarbonyl-6-(1-(2,6-dibromo-4-methylphenylimino)ethyl)pyridyl palladium dichloride
  参考文献：
  名称：

  Synthesis of palladium complexes containing 2-methoxycarbonyl-6-iminopyridine ligand and their catalytic behaviors in reaction of ethylene and norbornene

  摘要：

  A series of palladium complexes (C1-C7) have been prepared by the reaction of PdCl2(CH3CN)(2) with 2-methoxycarbonyl-6-iminopyridines, L1-L7. The 2-methoxycarbonyl-6-iminopyridines and their complexes were fully characterized by FT-IR, NMR spectra and elemental analysis. Structures of C1, C2, C4, C5 and C6, C7 were determined by X-ray crystallography, and these complexes fold slightly distorted square planar structures around palladium coordinated with two nitrogen atoms and two chlorides. These palladium complexes exhibited moderate catalytic activities for ethylene dimerization and/or polymerization in the presence of methylaluminoxane, and showed remarkable catalytic activity for norbornene polymerization. The catalytic behaviors of these complexes were highly affected by both the ligand employed and reaction conditions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.026