| 1447918-58-2

• CAS: 1447918-58-2
• 化学式: C₁₅H₁₆Cl₄N₄Pd₂
• 分子量: 606.971
• InChiKey: GKHWOAYVXJTNHR-NJVFXKOQSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 1-pyridin-2-yl-N-[3-(pyridin-2-ylmethylideneamino)propyl]methanimine 以 氯仿 、 乙腈 为溶剂， 反应 3.0h， 以93%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterization of mono- and dinuclear Ni^IIand Pd^IIcomplexes derived from tetradentate 1,7-bis-(pyridin-2-yl)-2,6-diaza-1,6-heptadiene

  摘要：

  The reaction of Schiff base 1,7-bis-(pyridin-2-yl)-2,6-diaza-1,6-heptadiene (L) with either NiCl26H2O or [(PdCl2)-Cl-II(CH3CN)(2)]/Na[BF4] in 1:1 stoichiometry yielded mononuclear ionic complexes, trans-[Ni-II(L)(H2O)(2)]Cl-23H2O (13H2O) and [Pd-II(L)][BF4](2) (2), respectively; the reaction of L with [(PdCl2)-Cl-II(CH3CN)(2)] in 1:2 ratio yielded dinuclear cis-[Pd-II (2)(-L)Cl-4] (3). Complexes 1-3 were characterized by vibrational spectroscopy and X-ray diffraction; diamagnetic 2 and 3 were also characterized by NMR in solution. The molecular structures of 1 and 2 displayed tetradentate coordination of L with formation of two five-membered and one six-membered chelate rings for both complexes. In 3, L showed bidentate coordination mode for each pyridylimine toward Pd-II. Complex 1 has distorted octahedral geometry around Ni-II and an extended hydrogen-bond network; distorted square planar geometry around Pd-II in 2 and 3 was observed.

  DOI：

  10.1080/00958972.2013.806985