Al(CH(CMeN(2,6-iPr2C6H3))2)[OB(3-CH3C6H4)]2(μ-O) | 1267671-53-3

• 英文名称: Al(CH(CMeN(2,6-iPr2C6H3))2)[OB(3-CH3C6H4)]2(μ-O)
• CAS: 1267671-53-3
• 化学式: C₄₃H₅₅AlB₂N₂O₃
• 分子量: 696.525
• InChiKey: FBYBYDQLBJIEDR-VCGBEGQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(HC(CMeN(2,6-i-Pr2C6H3))2)AlH2] 、 3-甲基苯硼酸 以 甲苯 为溶剂， 以85.1%的产率得到Al(CH(CMeN(2,6-iPr2C6H3))2)[OB(3-CH3C6H4)]2(μ-O)
  参考文献：
  名称：

  Synthesis of Boroxine-Linked Aluminum Complexes

  摘要：

  The reaction of LAIH(2) (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) (1) with 3-methylphenylboronic acid and 3-fluorophenylboronic acid resulted in the boroxine-linked aluminum compounds LAI[OB(3-CH3C6H4)](2)(mu-O) (2) and LAI[OB(3-PC6H4)](2)(mu-O) (3), respectively. LAI[OB(2-PhC6H4)(OH)](2) (4) was synthesized by the reaction of 1 with 2-biphenylboronic acid. Compound 4 is the intermediate analogue to those, which we postulated for the formation of 2 and 3. The reaction of 1 with 3-hydroxyphenylboronic acid resulted in the first metal benzoboroxole oxide LAI[OB(o-CH2O)C6H4](2) (5), which is formed from a compound with B-(OH)(2) and C-OH functionalities.

  DOI：

  10.1021/ic1022906