[Cu(PPh3)2(dipyrido[3,2-a:2',3'-c]phenazo-15-crown-5)]PF6 | 461038-82-4

• 英文名称: [Cu(PPh3)2(dipyrido[3,2-a:2',3'-c]phenazo-15-crown-5)]PF6
• CAS: 461038-82-4
• 化学式: C₆₂H₅₄CuN₄O₅P₂*F₆P
• 分子量: 1205.59
• InChiKey: QGIJBLWOIKYCLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  {Cu(I)(acetonitrile)2(triphenylphosphine)2}PF6 、 dipyrido[3,2-a:2',3'-c]phenazo-15-crown-5 以 二氯甲烷 为溶剂， 以62%的产率得到[Cu(PPh3)2(dipyrido[3,2-a:2',3'-c]phenazo-15-crown-5)]PF6
  参考文献：
  名称：

  Synthesis, luminescence and host–guest chemistry of copper(I) and zinc(II) complexes of dppzc (dppzc=dipyrido[3,2-a:2′,3′-c]phenazo-15-crown-5)

  摘要：

  Copper(l) and zinc(H) complexes containing dipyrido[3,2-a:2,3'-c]phenazo-15-crown-5 (dppzc) ligand have been synthesized and characterized, and their photophysics and electrochemistry studied. The crystal structure of [Zn(SC6H4-CH3-p)(2)(dppzc)] (2) has been determined. The ion-binding properties of these complexes towards alkali metal ions have also been described. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00809-5