| 231608-17-6

• CAS: 231608-17-6
• 化学式: BF₄*C₃₀H₂₉NO₂PPd
• 分子量: 659.764
• InChiKey: VXJHQNJRBHPMIX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙酸乙烯酯 、 以 二氯甲烷 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Study of Insertion of Olefins and/or Carbon Monoxide into Phosphine−Imine Palladium Methyl Complexes

  摘要：

  Palladium methyl complexes with a phosphine-imine (P similar toN) bidentate ligand, [Pd(P similar toN)-MeCl] (1), [Pd(P similar toN)Me(CH3CN)] (BF4) (2), and [Pd(P similar toN)Me(PPh3)] (BF4) (3), are treated with CO to result in the corresponding Pd-acyl complexes 4-6. NMR studies indicate the formation of a sole isomer with the acyl group cis to the phosphine donor. The neutral complex 4 and the triphenylphosphine-substituted complex 6 cannot serve for the insertion of ethylene. However, the acetonitrile complex 5 appears to be active in the insertion reaction with various alkenes as well as ethylene/CO (E-CO) co-oligomerization, resulting in the products 7-14 and 16, which have been isolated and characterized by spectroscopic methods. X-ray structures of 1, 2, 3, 4, 7, 10, 11, and 13 are revealed.

  DOI：

  10.1021/om000880q