| 195441-37-3

• CAS: 195441-37-3
• 化学式: C₁₀H₇Cl₃O₄SnW
• 分子量: 600.082
• InChiKey: IOHRJFFQQJTYAW-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  异烟肼 、 以 乙醇 为溶剂， 以87%的产率得到[μ-(C5H4(CH3)C=N-N=C(O)-4-C5H4NH)W(CO)3SnCl3]
  参考文献：
  名称：

  Synthesis and crystal structures of cyclodiazastannoxides fused cyclopentadienyl M–Sn (M = Mo, W) bonded organometallic heterocycle

  摘要：

  The condensation reaction of CH3COC5H4M(CO)(3)SnCl3 (M = Mo or W) with PyCONHNH2 (Py = 2,3,4-pyridyl or 2-pyridylmethyl) in mild conditions yields cyclodiazastannoxides fused cyclopentadienyl M-Sn bonded organometallic heterocycle {mu-[C5H4(CH3)C=N-N=C(O)PyH]M(CO)(3)SnCl3}. The similar reaction of CH3COC5H4M(CO)(3)SnCl3 with ArCONHNH2 (Ar = 2-furanyl) gives complexes mu-[C5H4(CH3)C=N-N=C(O)Ar]M(CO)(3)SnCl2(H2O), in which the water molecule can be replaced by other N-donor ligands, such as pyridine or 4,4-bipyridine. Arene-bridged organometallic heterocyclic complexes mu-{[C5H4(CH3)C=N-N=C(O)](2)C6H4}{M(CO)(3)SnCl2(Solvent)}(2) have also been prepared by the reaction of CH3COC5H4M(CO)(3)SnCl3 with terephthaloyl hydrazine. In these new organometallic heterocyclic complexes, it seems that the tin atom prefers to be six-coordinate through absorbing the chloridion or solvent molecules. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.027
• 作为产物：
  描述：

  盐酸 、 以 二氯甲烷 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  新型桥联环戊二烯基WSn（IV）键合双金属配合物的合成。的Cl晶体结构3 SnMo（CO）3 Ç 5 ħ 4（CH 3）CNNHC 6 ħ 3（NO 2）2和μ-[C 5 H ^ 4（CH 3）CNN（CO ）Ph] W（CO）3 SnCl 2 ·（EtOH）2

  摘要：

  CH的反应3 COC 5 ħ 4（CO）3 MoSnCl 3与2,4-二硝基苯肼，得到相应腙，氯3 SnMo（CO）3 Ç 5 ħ 4（CH 3）CNNHC 6 ħ 3（NO 2）2（1）。1的晶体是单斜晶体：，空间群，MoSn距离2.7040（7）Å。CH 3 COC 5 H 4（CO）3 WSnCl 3的反应与苯甲酰肼在回流的乙醇中，得到μ[C 5 H ^ 4（CH 3）CNNC（O）PH]WSnCl 2（C 2 H ^ 5 OH）2（2）。2的晶体是单斜晶体。，空间组Cc，Z = 4，WSn距离2.7767（9）Å。

  DOI：

  10.1016/s0022-328x(97)00416-6

文献信息

• New pentacoordinate bicyclodiazastannsulfide formed between the functionalized cyclopentadienyl ring and tin
  作者：Shan-Shan Chen、Yan-Ye Dou、Miao Du、Liang-Fu Tang

  DOI：10.1016/j.jorganchem.2006.05.010

  日期：2006.8

  New pentacoordinate bicyclodiazastannsulfide fused cyclopentadienyl M-Sn (M = Mo or W) bonded organometallic heterocycle mu-[C5H4(CH3)C=N-N=C(S)Ar]M(CO)(3)SnCl2} has been obtained by the condensation reaction of CH3COC5H4M(CO)(3)SnCl3 with arylthiocarboxyhydrazide (ArCSNHNH2, Ar = 2-furanyl, 2-thienyl, 2- or 4-hydroxyphenyl) in mild conditions. While the similar reaction of CH3COC5H4M(CO)(3)SnCl3 with ArCONHNH2 (Ar = 2- or 4-hydroxyphenyl) only gives non-cyclic compounds [C5H4(CH3)C=N-NHC(O)Ar]M(CO)(3)SnCl3, in which the tin atom remains tetracoordinate. In bicyclodiazastannsulfide the tin atom prefers to adopt pentacoordinate geometry, while in the corresponding bicyclodiazastannoxide the tin atom is hexacoordinate. In addition, phenylhydrazine, 2- or 4-hydroxyphenylcarboxyhydrazide is used to react with CH3COC5H4M(CO)(3)SnCl3, only tetracoordinate non-cyclic tin compound is obtained. (c) 2006 Elsevier B.V. All rights reserved.