[palladium(II)chloride(pyridine-2,6-di(C(CH3)NC6H4F))](palladium(II)trichloride) | 1245796-57-9

• 英文名称: [palladium(II)chloride(pyridine-2,6-di(C(CH3)NC6H4F))](palladium(II)trichloride)
• CAS: 1245796-57-9
• 化学式: C₂₁H₁₇ClF₂N₃Pd*Cl₃Pd
• 分子量: 704.035
• InChiKey: DGXJHRZRQKVARY-QXJDLJJCSA-J

反应信息

• 作为产物：
  描述：

  (Z,E)-2,6-bis[1-(4-fluorophenylimino)ethyl]pyridine 、 palladium dichloride 以 ethanol 为溶剂， 以90%的产率得到[palladium(II)chloride(pyridine-2,6-di(C(CH3)NC6H4F))](palladium(II)trichloride)
  参考文献：
  名称：

  Palladium(II) Complexes Containing 2,6-Bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions

  摘要：

  A series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change S*, enthalpy change H#, and Gibbs free energy change G# of the thermal decomposition were calculated by means of several methods based on the single heating rate.

  DOI：

  10.1080/15533174.2010.486822