| 487061-23-4

• CAS: 487061-23-4
• 化学式: Ge₈H₈O₂₀
• 分子量: 908.772
• InChiKey: YJRWFGXPHFZGQU-BNQMODEMSA-N

文献信息

• Utilization of cage germoxanes as templates for tuning pore characteristics of siloxane-based materials
  作者：Taiki Hayashi、Takamichi Matsuno、Kazuyuki Kuroda、Atsushi Shimojima

  DOI：10.1093/chemle/upae025

  日期：2024.3.1

  We demonstrate the utilization of cage germoxanes as templates for tuning the pore characteristics of siloxane-based materials. Molecular-scale composites of cage germoxanes and cage siloxanes were prepared by hydrosilylation reactions between SiH- and vinyl-modified cage siloxanes in the presence of vinyl-modified cage germoxanes. Subsequent acid treatments selectively removed the germoxane moiety, resulting in variation in the pore structures. These results contribute to developing a novel method for tuning the pore characteristics of siloxane-based nanoporous materials.