[(PtBr2Me2)2(μ-2,2'-bipyrimidine)] | 1144114-81-7

• 英文名称: [(PtBr2Me2)2(μ-2,2'-bipyrimidine)]
• 英文别名: [(PtBr2Me2)2(μ-2,2'-bpym)]
• CAS: 1144114-81-7
• 化学式: C₁₂H₁₈Br₄N₄Pt₂
• 分子量: 928.078
• InChiKey: IVBSLOYPBDBLLU-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  N,N-二甲基甲酰胺-d7 、 [(PtBr2Me2)2(μ-2,2'-bipyrimidine)] 以 N,N-二甲基甲酰胺-d7 为溶剂， 生成 [PtBr2Me2(2,2'-bipyrimidine)] 、 [PtBr2Me2(DMF-d7)2]
  参考文献：
  名称：

  Studies of mononuclear and dinuclear complexes of dibromodimethylplatinum(IV): Preparation, characterization and crystal structures

  摘要：

  A number of complexes of the types [PtBr2Me2(N-N)] (N-N = 4,4'-di-Me-2,2'-bpy (1); 4,4'-di-t-Bu-2,2'-bpy (2); 2,2'-bpz (3); bpym (4)) and [PtBr2Me2(L)(2)] (L = H-pz (5); 4-Me-H-pz (6); H-idz (7); H-im (8); H-bim (9); quaz (10)) are reported. Characterization by NMR (H-1, C-13 and Pt-195), IR and EI-MS is given. In addition, crystal structures of several of these complexes are described. Furthermore, interactions within these structures including intramolecular hydrogen bonding and pi-pi stacking interactions are reported. The reactivity of selected mononuclear complexes was investigated and yielded two dinuclear complexes [PPh4][(PtBrMe2)(2)(mu-Br)(mu-pz)(2)] (11) and [(PtBr2Me2)(2)(mu-bpym)] (12), respectively. The latter complex is accompanied by a solid-state structure. Finally, the thermal stability of all complexes is reported. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.06.025
• 作为产物：
  描述：

  2 2'-联嘧啶 、 [(PtMe₃)₄μ³-Br₄] 以 氯仿 为溶剂， 以99%的产率得到[(PtBr2Me2)2(μ-2,2'-bipyrimidine)]
  参考文献：
  名称：

  Studies of mononuclear and dinuclear complexes of dibromodimethylplatinum(IV): Preparation, characterization and crystal structures

  摘要：

  A number of complexes of the types [PtBr2Me2(N-N)] (N-N = 4,4'-di-Me-2,2'-bpy (1); 4,4'-di-t-Bu-2,2'-bpy (2); 2,2'-bpz (3); bpym (4)) and [PtBr2Me2(L)(2)] (L = H-pz (5); 4-Me-H-pz (6); H-idz (7); H-im (8); H-bim (9); quaz (10)) are reported. Characterization by NMR (H-1, C-13 and Pt-195), IR and EI-MS is given. In addition, crystal structures of several of these complexes are described. Furthermore, interactions within these structures including intramolecular hydrogen bonding and pi-pi stacking interactions are reported. The reactivity of selected mononuclear complexes was investigated and yielded two dinuclear complexes [PPh4][(PtBrMe2)(2)(mu-Br)(mu-pz)(2)] (11) and [(PtBr2Me2)(2)(mu-bpym)] (12), respectively. The latter complex is accompanied by a solid-state structure. Finally, the thermal stability of all complexes is reported. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.06.025