| 188444-47-5

• CAS: 188444-47-5
• 化学式: C₃₄H₂₃N₄O₄Ru*F₆P
• 分子量: 797.615
• InChiKey: NVUYLNLNYZASQN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 1,4-二羟基蒽醌 、 顺-双(2,2-二吡啶)二氯化钌(II) 水合物 在 LiOMe 作用下， 以 乙醇 、 氯仿 为溶剂， 以29%的产率得到
  参考文献：
  名称：

  The synthesis and characterization of monomeric complexes of Ru(bpy)2 with dihydroxyanthraquinones

  摘要：

  The monomeric complexes, Ru(bpy)(2)1,4-DHAQ(+) and Ru(bpy)(2)1,5-DHAQ(+) (bpy=2,2'-bipyridine and DHAQ=dihydroxyanthraquinone), were synthesized by the reaction of Ru(bpy)(2)Cl-2 . 2H(2)O with an excess of either 1,4-DHAQ or I,5-DHAQ. The complexes were purified chromatographically and characterized spectroscopically and electrochemically. Comparisons between the data for these monomers and data from the corresponding free ligands and ruthenium bipyridyl dimers were made. The lowest energy spectral transition in the visible region was assigned as an MLCT transition to the DHAQ based on the red shifting from monomer to the corresponding dimer and the solvatochromism of the transition. In aqueous solution the pK(a) for both the 1,4- and 1,5-DHAQ monomer was determined to be 10.1+/-0.2 and for the 1,8-DHAQ monomer, 10.5+/-0.2. In all cases, pK(al) of the uncomplexed dihydroxyanthraquinones was more acidic measured under the same conditions. From the properties of the coordinated DHAQs attempts were made to evaluate whether they were sigma donating or pi accepting.

  DOI：

  10.1016/s0020-1693(96)05351-0