| 1214278-50-8

• CAS: 1214278-50-8
• 化学式: C₆₀H₄₀Br₄N₈O₈Sb₄
• 分子量: 1807.64
• InChiKey: HGQLPQWINSXFJR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (p-bromophenyl)stibonic acid 、 2-(1H-吡唑-3-基)苯酚 以 甲苯 为溶剂， 以61.3%的产率得到
  参考文献：
  名称：

  Isolation of Tetranuclear Organoantimony Oxo Clusters and Hexa-decanuclear Polyoxostibonates

  摘要：

  Reaction of phenolic pyrazolyl ligands with arylstibonic acids afforded two novel tetranuclear clusters [(p-X-C6H4Sb)(4)(O)(5)(OH)(2)(HPhPzR(1))(4)] (where X = Cl, R-1 = Ph (1); X = Br, R-1 = Ph (2); X = Br, R-1 = t-Bu (3)) and [(p-Br-C6H4Sb)(4)(PhPz)(4)(O)(4)] (4). Depending on the steric bulk of the group present on the pyrazole ring, either one (1-3) or two (4) of the ring nitrogens have been found to coordinate to the metal atoms. Remarkably, when 3,5-DMPz is reacted with arylstibonic acid, hexa-decanuclear polyoxostibonates [(p-X-C6H4Sb)(16)(O)(28)(OH)(8)](3,5-DMPz)(6) (X = Cl (5), Br (6)) have been isolated.

  DOI：

  10.1021/om900942q