DMAB-CO2-Re(CO)3(phen) | 923570-56-3

• 英文名称: DMAB-CO2-Re(CO)3(phen)
• 英文别名: (4-(dimethylamino)benzoato)Re(CO)3(phen)
• CAS: 923570-56-3
• 化学式: C₂₄H₁₈N₃O₅Re
• 分子量: 614.631
• InChiKey: LVBKCKQWKUZZAU-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  DMAB-CO2-Re(CO)3(phen) 以 further solvent(s) 为溶剂， 生成 [DMAB-CO2-Re(CO)3(phen)](1+)
  参考文献：
  名称：

  On the nature of the redox products of 4-((CH3)2N)C6H4–CO2−and 4-((CH3)2N)C6H4–CO2–Re(CO)3(1,10-phenanthroline): A spectroelectrochemical, pulse radiolysis and flash photochemical study

  摘要：

  The UV-Vis absorption spectra of 4-dimethylaminobenzyl radical cation (DMAB(center dot+)) and 1,10-phenanthroline radical anion (phen(center dot-)) were obtained by spectroelectrochemistry, flash photolysis and pulse radiolysis experiments on DMAB-CO2-Re-I(CO)(3)(phen) and DMAB-COOH. DMAB-CO2-Re-I(CO)(3)(phen) was shown to have remarkable reversibly/stable redox processes under electrochemical perturbations. An excellent agreement was observed between the spectrum of the radical cation DMAB(center dot+) obtained electrochemically and radiolytically. The in situ UV-Vis spectrum of the electrochemically reduced radical anions, phen(center dot-), was compared with that obtained from the products of the reductive quenching of the corresponding photochemically excited states. Besides, the oxidative quenching of the Re-I complex excited states by [Ni-II(Me-6[14]-aneN(4))] showed the formation of [(DMAB(center dot+)-CO2)-Re-I(CO)(3)(phen)] as the main primary product. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.01.006