CpFe(CO)2CSeCOCO2Me | 928835-28-3

• 英文名称: CpFe(CO)2CSeCOCO2Me
• CAS: 928835-28-3
• 化学式: C₁₀H₈FeO₅Se
• 分子量: 342.978
• InChiKey: LABIYATYLAKPTG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲基戊酰氯 、 (μ-Se)[CpFe(CO)2]2 以 乙醚 为溶剂， 以65%的产率得到CpFe(CO)2CSeCOCO2Me
  参考文献：
  名称：

  O-Alkylthio- and O-alkylselenooxalate iron complexes: Structures of CpFe(CO)2ECOCO2Me and [CpFe(CO)2ECO]2

  摘要：

  When the iron sulfide complexes (mu-S-x)[CpFe(CO)(2)](2) (x = 2,3) are treated with O-alkyl oxalyl chlorides ROCOCOCl the complexes CpFe(CO)(2)SCOCO2R (1) [R = Me (a), Et (b)] are obtained. Similarly, the complexes CpFe(CO)(2)SeCOCO2R (2) are obtained from the analogous iron selenide (g-Se)[CpFe(CO)(2)](2) reaction with the same reagents. Treatment of the iron selenide with half equivalent of oxalyl chloride produces the dimeric complex [CpFe(CO)(2)SeCO](2) (3). The new complexes, 1, 2 and 3, have been characterized by elemental analyses, IR and H-1 NMR spectroscopy. The solid state structures of 1a, 2a, 3 and [CpFe(CO)(2)SCO](2) (4) were determined by an X-ray crystal structure analysis. (c) 2006 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2006.08.002