[C6Me6RuCl(aziridine)2]OTf | 1018682-37-5

• 英文名称: [C6Me6RuCl(aziridine)2]OTf
• 英文别名: [C6Me6RuCl(az)2]OTf
• CAS: 1018682-37-5
• 化学式: CF₃O₃S*C₁₆H₂₈ClN₂Ru
• 分子量: 534.005
• InChiKey: CJDDLGYPBCVSPR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙烯亚胺 、 [RuCl(C6Me6)(aziridine)2]Cl 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以70%的产率得到[C6Me6RuCl(aziridine)2]OTf
  参考文献：
  名称：

  Spectroscopic and structural characterization of cationic N-(2-aminoethyl)aziridine-N,N′ chelate complexes of the d6-metals Rh(III) and Ir(III)

  摘要：

  The syntheses of the compounds [M(Cp*)(aeaz)(az)](OTf)(2) (4, 5) (M = Rh(III), Ir(III); aeaz = C2H4NC2H4NH2, az = C2H4NH (3)) containing cationic N-(2-aminoethyl)aziridine-N,N' chelate complexes are described. The bis-aziridine complexes [MCl(Cp*)(az)(2)]Cl (M = Rh (1), M = Ir (2)) react with an excess of the aziridine (az) in the presence of AgO3SCF3 (=AgOTf) via AgCl precipitation and az addition followed by a metal-mediated coupling reaction, to give the compounds [M(Cp*)(aeaz)(az)](OTf)2 (4, 5). The new aeaz ligand is formally the dimerisation product of az. Using the same reaction conditions with the analogous, but weaker Lewis acidic ruthenium(II) complex [RuCl(C6Me6)(az)(2)]Cl (6) an anion exchange reaction yielding [RuCl(C6Me6)(az)(2)]OTf (8) is observed. After purification, all compounds are fully characterized using IR, FAB-MS, H-1 and C-13 NMR spectroscopy. The single crystal X-ray structure analysis reveals a distorted octahedral geometry for all complexes. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.023