| 482315-23-1

• CAS: 482315-23-1
• 化学式: C₃₇H₃₃N₂O₃PRu
• 分子量: 685.724
• InChiKey: DZYPVZTYNWWAHG-QPYPLYHUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 N,N'-二(2-羟基-alpha-甲基苄亚基)乙二胺 以 苯 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND BIOLOGICAL ACTIVITY OF RUTHENIUM(II) CARBONYL COMPLEXES CONTAINING TETRADENTATE SCHIFF BASES

  摘要：

  Several hexa-coordinated ruthenium(II) carbonyl complexes of the type [Ru(CO)(B)(L)] (B = PPh3, pyridine (py), piperidine (pip) or morpholine (morph); H2L = tetradentate Schiff bases) have been prepared by the reactions of [RuHCl(CO)(PPh3)2(B)] (B = PPh3 or py or pip or morph) with appropriate Schiff bases having the donor groups O,N viz., o-hydroxyacetophenoneethylenediimine, H-2(o-hyacen); o-hydroxyacetophenonepropylenediimine, H-2(o-hyacpn); o-hydroxyacetophenonetetramethylenediimine, H-2(o-hyactn), and o-hydroxyacetophenone-ortho-phenylenediimine, H-2(o-hyacopn), in 1:1 molar ratio. The complexes have been characterised on the basis of elemental analyses and spectral (IR, electronic, H-1 and P-31 NMR) data. The antibacterial activities of these new complexes were also tested.

  DOI：

  10.1081/sim-120014309