trans-dichlorobis(1,3-diaminopropane)ruthenium(III) chloride | 1360172-46-8

• 英文名称: trans-dichlorobis(1,3-diaminopropane)ruthenium(III) chloride
• CAS: 1360172-46-8
• 化学式: C₆H₂₀Cl₂N₄Ru*Cl
• 分子量: 355.681
• InChiKey: MZJJGEXRHKSKON-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  potassium aquapentachlororuthenate(III) 、 1,3-丙二胺 在 HCl 作用下， 以 甲醇 、 水 为溶剂， 以80%的产率得到trans-dichlorobis(1,3-diaminopropane)ruthenium(III) chloride
  参考文献：
  名称：

  Synthesis and bonding of trans-dichlorobis(1,3-diaminopropane)ruthenium(III) chloride to a self assembled monolayer and its effect on conducting polymer sheet conductivity

  摘要：

  We report the synthesis of trans-dichlorobis(1,3-diaminopropane)ruthenium(III) chloride. The molecular structure consists of a ruthenium metal complex and a chloride counterion. Electronic spectra of the solid complexes indicate an octahedral geometry around the ruthenium(III) metal center. We observe a UV-broadened band at 350 nm, a common absorption band in trans-ruthenium(III) amine and haloamine complexes. We also report, the single-crystal X-ray structures of the titled complex. The complex was shown to form a self assembled monolayer on quartz, which is a suitable substrate for deposition of conducting polymer PANI, PEDOT and PPy. We discuss key parameters which can be adjusted to tune both the physical properties of the Ru(III) surfaces and the sheet conductivity of the deposited conducting polymers thin films. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.059