[Ru(bpyOH)2(acac)][PF6] | 1228260-50-1

• 英文名称: [Ru(bpyOH)2(acac)][PF6]
• 英文别名: [Ru(4-(Me2OHCCC-2,2'-bipyridine)2(acetylacetone(-H))][PF6]
• CAS: 1228260-50-1
• 化学式: C₃₅H₃₅N₄O₄Ru*F₆P
• 分子量: 821.721
• InChiKey: YSUPSXDLFZNTJD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Ru(bpyBr)2(acac)][PF6] 、 2-甲基-3-丁炔-2-醇 在 Cu/Pd(PPh₃)4 catalyst 作用下， 以 dimethylformamide 、 further solvent(s) 为溶剂， 以76%的产率得到[Ru(bpyOH)2(acac)][PF6]
  参考文献：
  名称：

  Synthesis and characterization of β-diketonato ruthenium(II) complexes with two 4-bromo or protected 4-ethynyl-2,2′-bipyridine ligands

  摘要：

  Two new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)(2)(acac)](PF(6)) (2; bpyBr = 4-Bromo-2,2'-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)(2)(acac)](PF(6)) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2'-bipyridine) were prepared as candidates for building blocks. The (1)H NMR, (13)C NMR, UV-Vis, electrochemistry and FAB mass spectral data of these complexes are presented. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.057