[(η-C5H5BMe)Rh(1,5-cyclooctadiene)] | 60552-38-7

• 英文名称: [(η-C5H5BMe)Rh(1,5-cyclooctadiene)]
• CAS: 60552-38-7
• 化学式: C₁₄H₂₀BRh
• 分子量: 302.029
• InChiKey: LAFSGGWLMPVLNQ-GCOBPYNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(η-C5H5BMe)Rh(1,5-cyclooctadiene)] 、 溴 以 乙醚 为溶剂， 以59%的产率得到bis[dibromo(η-boratabenzene)rhodium]
  参考文献：
  名称：

  Synthesis and structure of (boratabenzene)rhodacarborane (η-7,8-C2B9H11)Rh(η-C5H5BMe)

  摘要：

  通过环辛二烯衍生物(η-C5H5BMe)Rh(1,5-C8H12)与Br2反应合成溴化物络合物[(η-C5H5BMe)RhBr2]2 (1)。化合物1与Tl[Tl(η-7,8-C2B9H11)]的反应得到(硼酸苯)若达卡硼烷(η-7,8-C2B9H11)Rh-(η-C5H5BMe)(2)。通过X射线衍射确定了化合物2的结构

  DOI：

  10.1007/s11172-010-0129-9

文献信息

• Triple-Decker Complexes. 12.¹ Triple-Decker Complexes with Bridging Boratabenzene Ligands. Syntheses, Structures of [(μ-C₅H₅BMe)(FeCp*)₂]PF₆ and of [(μ-C₅H₅BMe){Rh(COD)}₂]CF₃SO₃, and Boratabenzene Transfer Reactions
  作者：Gerhard E. Herberich、Ulli Englert、Beate Ganter、Christian Lamertz

  DOI：10.1021/om960536m

  日期：1996.11.26

  The orange complex Cp*Fe(C(5)H(5)BMe) (1a) was synthesized from [Cp*Fe(NCMe)(3)]PF6 and Li(C(5)H(5)BMe) in 91% yield. Electrophilic stacking reactions with metalloelectrophiles gave the triple-decker salts [(mu-C(5)H(5)BMe)(FeCp*)(2)]PF6 (4), [(mu-C(5)H(5)BMe)(FeCp*)(RuCp*)]CF3SO3 (5), and [(mu-C(5)H(5)BMe)(FeCp*)(MCp**)](CF3SO3)(2) with M = Rh (for 6) and M = Ir (for 7). Electrophilic stacking of Rh(C(5)H(5)BMe)(COD) (8) with [(COD)Rh(MeNO(2))(x)]CF3SO3 gave [(mu-C(5)H(5)BMe)Rh(COD)}2CF3SO3 (10). The structures of the two triple-decker complexes 4 and 10 were determined by X-ray diffraction. Boratabenzene transfer reactions were found for the heterobimetallic salts 5-7.