dichlorobis(acetophenonethiosemicarbazone)mercury(II) | 200125-17-3

• 英文名称: dichlorobis(acetophenonethiosemicarbazone)mercury(II)
• CAS: 200125-17-3；1072450-04-4；80005-29-4
• 化学式: C₁₈H₂₀Cl₂HgN₆S₂
• 分子量: 656.025
• InChiKey: WNXBZMMXTFJUCO-UTUIWUMXSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯乙酮硫代氨基甲酰肼 、 氯化苯汞 以 乙醇 为溶剂， 以55%的产率得到dichlorobis(acetophenonethiosemicarbazone)mercury(II)
  参考文献：
  名称：

  Synthesis and NMR spectroscopy of dichlorobis (acetophenonethiosemicarbazone) mercury (II) formed from phenylmercury (II) chloride and acetophenonethiosemicarbazone: the first example of symmetrisation in organomercury (II)-thiosemicarbazone chemistry

  摘要：

  The reaction of phenylmercury(II) chloride with acetophenonethiosemicarbazone (Hatsc) in ethanol in 1:1 mole ratio undergoes symmetrisation forming the products, HgCl2(Hatsc)(2) and Ph2Hg instead of the anticipated compound PhHgCl(Hatsc). The analytical data, some physical properties, IR and NMR (H-1, C-13, Hg-199) spectroscopy all support the formation of HgCl2(Hatsc)(2). Hg-199 NMR of the solid obtained from the filtrate of the reaction provides evidence for Ph2Hg. This reaction represents the first example of a symmetrisation phenomenon observed in organomercury(II)-thiosemicarbazone chemistry. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05574-6