3,4-diphenyl-1H-pyrrole-2,5-dicarboxylic acid bisferrocenylamide | 475148-12-0

• 英文名称: 3,4-diphenyl-1H-pyrrole-2,5-dicarboxylic acid bisferrocenylamide
• CAS: 475148-12-0
• 化学式: C₃₈H₃₁Fe₂N₃O₂
• 分子量: 673.377
• InChiKey: RNTCRDAPYIGITF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  aminoferrocene 、 3,4-diphenylpyrrole-2,5-dicarboxylic acid chloride 在 triethylamine 、 DMAP (catalyst) 作用下， 以 二氯甲烷 为溶剂， 以13%的产率得到3,4-diphenyl-1H-pyrrole-2,5-dicarboxylic acid bisferrocenylamide
  参考文献：
  名称：

  Mono- and bis-ferrocene 2,5-diamidopyrrole clefts: solid-state assembly, anion binding and electrochemical properties

  摘要：

  Four amido-pyrrole cleft anion receptors bearing one or two ferrocene reporter groups have been synthesised and crystallographically characterised. The receptors contain either a non-conjugated (1 and 3) or conjugated (2 and 4) link between the anion binding amido-pyrrole unit and the ferrocene reporter groups. The anion binding affinities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by H-1 NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01401-8

文献信息

• Anion complexation and electrochemical behaviour of ferrocene-appended amido-pyrrole cleftsElectronic supplementary information (ESI) available: 1H and 13C NMR spectra of 1 and 2, 1H NMR titrations of 1 and 2 with various putative anionic guests and with chloride following ferrocene CH resonances. See http://www.rsc.org/suppdata/nj/b2/b202989h/
  作者：Guy Denuault、Philip A. Gale、Michael B. Hursthouse、Mark E. Light、Colin N. Warriner

  DOI：10.1039/b202989h

  日期：2002.6.24

  Two amido-pyrrole cleft anion receptors bearing two ferrocene reporter groups have been synthesised and crystallographically characterised; the receptors contain either a non-conjugated or conjugated link between the anion-binding amido-pyrrole unit and the ferrocene reporter groups. The anion binding affinities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.

  已合成并表征了带有两个二茂铁报道基团的两种酰胺-吡咯裂隙阴离子受体；受体在阴离子结合酰胺基吡咯单元和二茂铁报告基团之间包含非共轭或共轭连接。分别通过 1 H NMR 滴定技术和使用 Pt 微盘工作电极的循环伏安法研究了在不存在和存在阴离子的情况下受体的阴离子结合亲和力和电化学行为。