| 1210476-96-2

• CAS: 1210476-96-2
• 化学式: C₃₈H₃₆N₃O₂P₂RuS₂*F₆P
• 分子量: 938.836
• InChiKey: SLQRTTPLWYIWJB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 mer-RuCl3(NO)(1,4-bis(diphenylphosphino)butane) 、 2-巯基吡啶 在 triethylamine 作用下， 以 甲醇 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  Dependence of the product on the P–P ligand in reactions of [RuCl3(NO)(P–P)] complexes (P–P = aromatic diphosphines) with 2-mercaptopyridine

  摘要：

  This study presents the syntheses and characterization of 2-mercaptopyridine (pyS(-)) complexes containing ruthenium(II) with the following general formula [Ru(pyS)(2)(P-P)], P-P = (c-dppen) = cis-1,2-bis(diphenylphosphino)ethylene) (1); (dppe)=1,2-bis(diphenylphosphino)ethane (2); (dppp)=1,3-bis(diphenylphosphino)propane (3) and (dppb) = 1,4-bis(diphenylphosphino)butane (4). The complexes were synthesized from the mer- or fac-[RuCl3(NO)(P-P)] precursors in the presence of triethylamine in methanol solution with dependence of the product on the P-P ligand. The reaction of pyS- with a ruthenium complex containing a bulky aromatic diphosphine dppb disclosed a major product with a dangling coordinated dppbO-P, the [Ru(pyS)(2)(NO)(eta(1)-dppbO-P)]PF6 (5). In addition, this work also presents and discusses the spectroscopic and electrochemical behavior of 1-5. and report the X-ray structures for I and S. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.09.004