[Rh(η5-C5Me5)(C3S5)]2 | 676340-65-1

• 英文名称: [Rh(η5-C5Me5)(C3S5)]2
• CAS: 676340-65-1
• 化学式: C₂₆H₃₀Rh₂S₁₀
• 分子量: 868.995
• InChiKey: FMJHUWVLFARKCP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Rh(η5-C5Me5)(C3S5)]2 、 溴 以 二氯甲烷 为溶剂， 以40%的产率得到[RhBr(η5-C5Me5)(C3S5)]
  参考文献：
  名称：

  Crystal structures of [Rh(η5-C5H5)(C3S5)] and [Rh(η5-C5Me5)(C3S5)]2 and properties of their oxidized species

  摘要：

  [Rh(eta(5)-C5H5)(C3S5)] and [Rh(eta(5) -C5Me5)(C3S5)](2)[C3S52- = 4,5-disulfanyl-1,3-dithiole-2-thionate(2-)] were prepared by reactions of [NMe4](2)[C3S5] with [Rh(eta(5)-C5H5)Cl-2](2) and [Rh(eta(5)-C5Me5)Cl-2](2), respectively. Their X-ray crystal structural analyses revealed a monomeric form for the former complex and a dimeric geometry containing bridging S-Rh-S bonds for the latter in the solid state. They were reacted with bromine to afford [RhBr(L)(C3S5)] (L=eta(5)-C5H5 and eta(5)-C5Me5) with the Rh-Br bond and one electron-oxidation on the C3S5 ligand. ESR spectra and spin densities for these oxidized species are discussed. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.050
• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 tetramethylammonium 4,5-disulfanyl-1,3-dithiole-2-thionate(2-) 以 乙醇 、 二氯甲烷 为溶剂， 生成 [Rh(η5-C5Me5)(C3S5)]2
  参考文献：
  名称：

  Crystal structures of [Rh(η5-C5H5)(C3S5)] and [Rh(η5-C5Me5)(C3S5)]2 and properties of their oxidized species

  摘要：

  [Rh(eta(5)-C5H5)(C3S5)] and [Rh(eta(5) -C5Me5)(C3S5)](2)[C3S52- = 4,5-disulfanyl-1,3-dithiole-2-thionate(2-)] were prepared by reactions of [NMe4](2)[C3S5] with [Rh(eta(5)-C5H5)Cl-2](2) and [Rh(eta(5)-C5Me5)Cl-2](2), respectively. Their X-ray crystal structural analyses revealed a monomeric form for the former complex and a dimeric geometry containing bridging S-Rh-S bonds for the latter in the solid state. They were reacted with bromine to afford [RhBr(L)(C3S5)] (L=eta(5)-C5H5 and eta(5)-C5Me5) with the Rh-Br bond and one electron-oxidation on the C3S5 ligand. ESR spectra and spin densities for these oxidized species are discussed. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.050