| 1330094-60-4

• CAS: 1330094-60-4
• 化学式: C₂₂H₃₄BNO₅Si
• 分子量: 431.412
• InChiKey: SXGFSYORNGQXAM-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  频哪醇 、 在 NaHCO₃ 作用下， 以 甲醇 为溶剂， 生成 triisopropyl((2-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)vinyl)oxy)silane
  参考文献：
  名称：

  Amphoteric α-Boryl Aldehydes

  摘要：

  A new class of stable molecules, alpha-boryl aldehydes, has been prepared from oxiranyl N-methyliminodiacetyl boronates by a 1,2-boryl migration with concomitant epoxide scission. A range of boryl imines, alkenes, alcohols, acids, enol ethers, enamides, and other functionalized boronic acid derivatives that are difficult or impossible to prepare using established protocols can be accessed from alpha-boryl aldehydes. The chemoselective transformations of these building blocks, including the facile synthesis of functionalized unnatural amino acids from silyloxy and amido vinyl boronates, attest to the potential of alpha-boryl aldehydes in chemical synthesis.

  DOI：

  10.1021/ja205910d