{tin(IV)(2-OCOCH3-C6H4CO2)2(5,10,15,20-tetraphenylporphyrin)}(CF3SO3)2 | 134343-69-4

• 英文名称: {tin(IV)(2-OCOCH3-C6H4CO2)2(5,10,15,20-tetraphenylporphyrin)}(CF3SO3)2
• CAS: 134343-69-4
• 化学式: C₆₂H₄₂N₄O₈Sn
• 分子量: 1089.75
• InChiKey: SFAAZSNWTOCKOK-NBICUONBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  阿司匹林 、 Dihydroxo(5,10,15,20-tetraphenylporphyrinato)tin(IV) 以 氯仿 为溶剂， 以89%的产率得到{tin(IV)(2-OCOCH3-C6H4CO2)2(5,10,15,20-tetraphenylporphyrin)}(CF3SO3)2
  参考文献：
  名称：

  Tin(IV) porphyrin complexes—IV. Crystal structures of meso-tetraphenylporphyrinatotin(IV) complexes with hydroxide, water, benzoate, salicylate and acetylsalicylate as axial ligands

  摘要：

  A series of five complexes of tin(IV) with 5,10,15,20-tetraphenylporphyrin (H2tpp) of the type [SnX2(tpp)] has been prepared and characterized using NMR and single crystal X-ray diffraction techniques. The complexes are [Sn(OH)2(tpp)] (1), [Sn(OH2)2(tpp)] (CF3SO3)2 (2), [Sn(C6H5CO2)2(tpp)] (3), [Sn(2-OH-C6H4CO2)2(tpp)] (4) and [Sn(2-OCOCH3-C6H4CO2)2(tpp)] (5). All complexes are monomeric with little structural variation within the Sn(tpp) framework. All axial substituents act as unidentate ligands with the Sn-O bond lengths varying from 2.017(4) angstrom (X = OH) (1) through 2.055(5) angstrom (3), 2.06(3) angstrom (mean) (5), 2.09(1) angstrom (4) (the substituted benzoates) to 2.16(1) angstrom (mean) (X = OH2) (2).

  DOI：

  10.1016/s0277-5387(00)80221-1