| 354145-91-8

• CAS: 354145-91-8
• 化学式: BF₄*C₄₇H₆₆NOPdS₃
• 分子量: 950.47
• InChiKey: WPPDJADGVQDOPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 、 silver tetrafluoroborate 在 MeCN 作用下， 以 二氯甲烷 、 水 为溶剂， 生成
  参考文献：
  名称：

  Chemistry on Surface-Confined Molecules:  An Approach to Anchor Isolated Functional Units to Surfaces

  摘要：

  The synthesis of surface-confined, nanometer-sized dendrimers and Au nanoparticles was performed starting from single Pd-II pincer adsorbate molecules (10) embedded as isolated species into 11-mercapto-1-undecanol and decanethiol self-assembled monolayers (SAMs) on gold. The coordination of monolayer-protected Au nanoclusters (MPCs) bearing phosphine moieties at the periphery (13), or dendritic wedges (8) having a phosphine group at the focal point, to SAMs containing individual Pd-II pincer molecules was monitored by tapping mode atomic force microscopy (TM AFM). The individual Pd-II pincer molecules embedded in the decanethiol SAM were visualized by their coordination to phosphine MPCs 13; isolated objects with a height of 3.5 +/- 0.7 nm were observed by TM AFM. Reaction of these embedded Pd-II pincer molecules with the dendritic wedge 8 yielded individual molecules with a height of 4.3 +/- 0.2 nm.

  DOI：

  10.1021/ja010257c