[((2-α-pyridylethyl)tris(phenyl)phosphonium)trichlorozinc(II)](MeCN) | 946864-01-3

• 英文名称: [((2-α-pyridylethyl)tris(phenyl)phosphonium)trichlorozinc(II)](MeCN)
• CAS: 946864-01-3
• 化学式: C₂H₃N*C₂₅H₂₃Cl₃NPZn
• 分子量: 581.24
• InChiKey: MGTQUHRBZBGFMT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三苯基膦 、 乙腈 、 zinc(II) chloride 、 5-(2-pyridyl)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 以 乙腈 为溶剂， 以17%的产率得到[((2-α-pyridylethyl)tris(phenyl)phosphonium)trichlorozinc(II)](MeCN)
  参考文献：
  名称：

  Synthesis and crystal structure of {(2-α-pyridylethyl)tris(phenyl)phosphonium}trichlorozinc(II)

  摘要：

  The structure of the complex {(2-alpha-pyridylethyl)tris(phenyl)phosphonium}trichlorozinc(II), which is an unexpected product of the reaction of the Zn2+ ion with coordinated 4,5-(2-pyridylethylene)dithio-1, 3-dithiol-2-thione, is described. The reaction mechanism is studied by the ESI method of positive and negative ions. The crystals are monoclinic, space group P2(1)/c, a=16.129(3) angstrom, b=11.167(2) angstrom, c=14.874(3) angstrom, beta=91.77(3)degrees, Z=4. The Zn(II) atom has a quasi-tetrahedral environment of three chloride ions and one phosphonium cation coordinated at the nitrogen atom of the pyridyl fragment.

  DOI：

  10.1134/s1070328406110054