| 1154406-22-0

• CAS: 1154406-22-0
• 化学式: C₃₄H₃₃AlN₄
• 分子量: 524.644
• InChiKey: IBJZOIUBRJDVHA-ZOSRWJCSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-N-phenylamino-4-N-phenylimino-2-pentene 在 LiC(Si(CH₃)3)3*2THF 作用下， 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Reactions of β-diketiminatoaluminum hydrides with tert-butyl hydrogenperoxide – Facile formation of dialuminoxanes containing Al–O–Al groups

  摘要：

  Treatment of diphenyl-beta-diketiminatoaluminum dihydride, LAlH(2) [1, L = {H(5)C(6)-N = C(Me)}(2)CH] with neo-pentyl- or trimethylsilylmethyllithium afforded the corresponding alkylderivatives LAlH(R) [R = CH(2)-SiMe(3) (2), CH(2)-CMe(3) (3)] by the precipitation of lithium hydride. Deprotonation of a methyl group instead of salt elimination occurred by the similar reaction of the more basic alkyllithium compound LiC (SiMe(3))(3). The reactions of the hydrides 1-3 with tert-butyl hydrogenperoxide did not yield the expected peroxo derivatives, instead the dialuminoxanes LAl(R)-O-Al(R)L [R = OCMe(3) (5), CH(2)SiMe(3) (6), CH(2)CMe(3) (7)] were isolated in high yields. Their Al-O-Al bridges deviated from linearity and had Al-O-Al bond angles of about 155 degrees on average. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.09.036