| 162931-94-4

• CAS: 162931-94-4
• 化学式: C₂₀H₃₈FeP₂
• 分子量: 396.316
• InChiKey: MKXNBKVHIKCTNR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {(η5-C6H7)(hydrido)(i-Pr)P(CH2)2P(i-Pr)2}Fe 、 甲苯 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  之二的制备（η 3 -烯丙基）铁（II）络合物及其反应用的1,3-二烯

  摘要：

  The title compounds were prepared by treating Fe(PR(3))(2)Cl-2 or Fe(R(2)P(CH2)(n)PR(2))Cl-2 with allylmagnesium chloride. Some of them were also made by reaction of Fe(PR(3))(2)Cl-2 with isopropylmagnesium chloride, or with active-magnesium and allyl chloride, or by reaction between tris(eta(3)-allyl)iron and bis(dimethylphosphino)ethane. The new compounds were characterized by NMR spectroscopy and shown to be formed as a mixture of two isomers that differ in the mutual arrangement of the two allyl groups. The reactions of the bis(allyl)iron compounds with 1,3-dienes were studied: complexes containing eta(4)-1,3-C4H6, eta(4)-1-C3H5C4H5 or eta(5)-l-ethylcyclohexadienyl groups were isolated from the reaction with 1,3-butadiene. The reaction between (eta(3)-C3H5)(2)Fe((Pr2PC2H4PPr)-Pr-i-Pr-i(2)) and 1,3-cyclohexadiene gave (eta(5)-cyclohexadienyl)Fe((Pr2PC2H4PPr2)-Pr-i-Pr-i)H.

  DOI：

  10.1016/0022-328x(94)88046-8

文献信息

• Iron(0) arene and iron(II) hydride complexes from the hydrogenation or thermolysis of high-spin iron(II) alkyls
  作者：Ann R. Hermes、Timothy H. Warren、Gregory S. Girolami

  DOI：10.1039/dt9950000301

  日期：——

  [Fe(CH2C6H4Me-p)2(dippe)] in toluene gave a mixture of several products: the iron(0) arene complexes [Fe(η6-C6H4Me2-1,4)(dippe)] and [Fe(η6-C6H5Me)(dippe)], the iron (II) monohydride [Fe(η5-C6H5Me2-1,4)H(dippe)], where the 1,4-dimethylcyclohexadienyl ligand arises from addition of two hydrogen atoms to a p-methylbenzyl group, and the iron(II) dihydride [FeH2(dippe)2]. Further experiments suggest that these products

  研究了氢与化学计量比为[FeR 2（dippe）] [dippe = 1,2-双（二异丙基膦基）乙烷]的14电子高自旋铁（II）二烷基的反应。的p -甲基苄基中的二乙醚络合物，得到零价p二甲苯复杂的[Fe（η 6 -C 6 H ^ 4我2 -1,4-）（dippe）]，其中所述配体芳烃已通过加入氢原子所形成到的α碳p甲基苄基。[Fe（CH 2 C 6 H 4 Me- p）2的氢化（dippe）]在甲苯中得到的几种产物的混合物：铁（0）芳烃络合物的[Fe（η 6 -C 6 H ^ 4我2 -1,4-）（dippe）]和[铁（η 6 -C 6 ħ 5 ME）（dippe）]，铁（II）一水合物的[Fe（η 5 -C 6 ħ 5我2 -1,4-）H（dippe）]，其中所述1,4- dimethylcyclohexadienyl配体来源于加成的两个氢原子形成一个对甲基苄基，以及二氢化铁（II）[FeH