[(CO)3Mn(I)(1,2-bis(diphenylphosphino)ethane)(NCO)] | 145088-66-0

• 英文名称: [(CO)3Mn(I)(1,2-bis(diphenylphosphino)ethane)(NCO)]
• CAS: 145088-66-0
• 化学式: C₃₀H₂₄MnNO₄P₂
• 分子量: 579.41
• InChiKey: SAVPWOYVRBTKLM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(CO)3Mn(I)(1,2-bis(diphenylphosphino)ethane)(NCO)] 在 HBr 作用下， 以 甲醇 为溶剂， 以83-87的产率得到fac-[bromo(1,2-bis(diphenylphosphino)ethane)tricarbonylmanganese(I)]
  参考文献：
  名称：

  The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO

  摘要：

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

  DOI：

  10.1016/s0277-5387(00)83162-9
• 作为产物：
  描述：

  [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF4) 在 NaN₃ 作用下， 以 甲醇 为溶剂， 以86-90的产率得到[(CO)3Mn(I)(1,2-bis(diphenylphosphino)ethane)(NCO)]
  参考文献：
  名称：

  The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO

  摘要：

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

  DOI：

  10.1016/s0277-5387(00)83162-9