(η6-hexamethylbenzene) ruthenium(II)Cl[N-(2-pyridinylmethylene)-p-nitrophenylamine] PF6 | 635750-67-3

• 英文名称: (η6-hexamethylbenzene) ruthenium(II)Cl[N-(2-pyridinylmethylene)-p-nitrophenylamine] PF6
• CAS: 635750-67-3
• 化学式: C₂₄H₂₇ClN₃O₂Ru*F₆P
• 分子量: 670.984
• InChiKey: UAQFSJGMIFIXBC-GPZOHOMCSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [RuCl2(hexamethylbenzene)]2 、 2-<(4-nitrophenyl)iminomethyl>pyridine 以 二氯甲烷 为溶剂， 生成 (η6-hexamethylbenzene) ruthenium(II)Cl[N-(2-pyridinylmethylene)-p-nitrophenylamine] PF6
  参考文献：
  名称：

  Syntheses and characterization of arene ruthenium (II) complexes containing N,N′-donor Schiff base ligands. Crystal and molecular structure of [(η6-C6Me6)Ru(C5H4N-2-CHNC6H4-p-NO2)]PF6

  摘要：

  Reaction of [(eta(6)-C6Me6)RuCl2](2) (1a) with N,N'-donor Schiff bases viz., para- substituted N-(2-pyridinylmethylene)phenylamines yielded complexes of the formulation [(eta(6)-C6Me6)Ru(C5H4N-2-CH=N-C6H4-p-X)Cl](+) 2a-e where C6Me6 = hexamethylbenzene, X = H (2a), CH3 (2b), OCH3 (2c) Cl (2d) and NO2 (2e). Reaction of 1a and [(eta(6)-p-cymene)RuCl2](2) (1b) where p-cymene = (CH3C6H4CH(CH3)(2)) with N-(2-pyridinylmethylene)cyclohexylamine (2-PC) yielded complexes of the type [(eta(6)-arene)Ru(2-PC)Cl](+) (arene = C6Me6 (3a); p -cymene, (3b)) respectively. All these complexes were isolated as their PF6 salt. These complexes were characterized by spectroscopic and analytical data. The molecular structure of [(eta(6)-C6Me6)Ru(C5H4N-2-CH=N-C6H4-p-NO2)Cl]PF6 2e has been determined by X-ray crystallography. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01430-4