(η(5)-C5H5)Fe(η(5)-C5H4CH=CHCH=N-η5-C5H4)Fe(η(5)-C5H5) | 217465-02-6

• 英文名称: (η(5)-C5H5)Fe(η(5)-C5H4CH=CHCH=N-η5-C5H4)Fe(η(5)-C5H5)
• CAS: 217465-02-6
• 化学式: C₂₃H₂₁Fe₂N
• 分子量: 423.12
• InChiKey: IJPHDJGELRIYTO-LMNHIEIQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  aminoferrocene 、 3-ferrocenyl-2-propenal 以 甲苯 为溶剂， 以43%的产率得到(η(5)-C5H5)Fe(η(5)-C5H4CH=CHCH=N-η5-C5H4)Fe(η(5)-C5H5)
  参考文献：
  名称：

  Ferrocenyl-substituted imine ligands and their reactivity towards Fe2(CO)9; crystal structure of FcC(H)C(H)C(H)NC6H11 and (η4R1C(H)C(H)C(H)NR2)Fe(CO)3 (R1C6H5, R2Fc; R1Fc, R2C6H11, R1R2Fc; Fc(η5-C5H5) Fe(η5-C5H4))

  摘要：

  The synthesis of l-azadiene Ligands bearing ferrocenyl groups either at the C- or N-terminus or on both sides of the ligand from alpha,beta-unsaturated aldehydes and the corresponding amine is described. The reaction of these imine ligands with Fe-2(CO)(9) produces mononuclear iron complexes of the general formula (eta(4)-1-azadiene) Fe(CO)(3). The molecular structure of one of the I-azadiene ligands as well as those of three iron complexes were determined by X-ray structure analyses. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00180-7