| 231630-34-5

• CAS: 231630-34-5
• 化学式: C₁₄H₁₁IO₂Ru
• 分子量: 439.215
• InChiKey: YNGMFBJVGIFTDL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 碘 以 四氯化碳 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  A tetraruthenium carbonyl cluster bearing indenyl-type ligand as the facial bonding mode

  摘要：

  A tetraruthenium carbonyl cluster, (mu(3):eta(1):eta(3):eta(5)-3,4,5-trihydroacenaphthylenyl)Ru4H(CO)(9) (3), was synthesized from (mu(3):eta(1):eta(5)-dihydroacenaphthylene)Ru3H2(CO)(12) (2) in chloroform. The molecular structure showed the trihydroacenaphthylenyl ligand to be a rare example of triply bridging nine electron donor ligands, being bound to three ruthenium atoms by the face-capping mode. One ruthenium atom was bonded by the pi-cyclopentadienyl coordination mode, whereas the latter two were bound to four carbons in the six-membered ring by the eta(1):eta(3)-bonding mode. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01155-3