dichloro[1-methyl-2-(naphthyl-β-azo)imidazole]platinum(II) | 295806-52-9

• 英文名称: dichloro[1-methyl-2-(naphthyl-β-azo)imidazole]platinum(II)
• CAS: 295806-52-9
• 化学式: C₁₄H₁₂Cl₂N₄Pt
• 分子量: 502.262
• InChiKey: XOUQBKMRVYOZBN-ISQLRVRESA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  4-甲基吡啶 、 dichloro[1-methyl-2-(naphthyl-β-azo)imidazole]platinum(II) 、 sodium perchlorate 在 AgNO₃ 作用下， 以 乙腈 为溶剂， 生成 bis(4-methylpyridine)[1-methyl-2-(naphthyl-β-azo)imidazole]platinum(II) perchlorate monohydrate
  参考文献：
  名称：

  Synthesis, spectral and electrochemical properties of 1-alkyl-2-(naphthyl-β-azo)imidazole complexes of platinum(II) and the reaction with pyridine bases. Single-crystal X-ray structure of dichloro-[1-ethyl-2-(naphthyl-β-azo)imidazole]platinum(II)

  摘要：

  1-Alkyl-2-(naphthyl-beta-azo)imidazoles (beta-NaiX, X=Me (3a),Et (3b), and CH2Ph (3c)) have been synthesized and reacted with K2PtCl4 in boiling MeCN-water ( 1:1, v/v) and Pt(beta-NaiX) Cl-2 (4) are isolated as orange-brown products. IR spectra support cis-PtCl2 configuration and the structural configuration has been carried out by the X-ray diffraction study of Pt(beta-NaiEt)Cl-2 (4b). The treatment of aqueous silver nitrate solution, followed by the addition of pyridine bases (Rpy) and NaClO4 to an acetonitrile solution of Pt(beta-NaiX)Cl-2 under boiling conditions has yielded [Pt(beta-NaiX)(Rpy)(2)] (ClO4)(2) (5-7). The structure has been established by spectroscopic data (IR, UV-Vis, H-1 NMR). The redox properties of the complexes exhibit azo reductions. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00385-5
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 1-methyl-2-(naphthyl-β-azo)-imidazole 以 水 、 乙腈 为溶剂， 以73%的产率得到dichloro[1-methyl-2-(naphthyl-β-azo)imidazole]platinum(II)
  参考文献：
  名称：

  Synthesis, spectral and electrochemical properties of 1-alkyl-2-(naphthyl-β-azo)imidazole complexes of platinum(II) and the reaction with pyridine bases. Single-crystal X-ray structure of dichloro-[1-ethyl-2-(naphthyl-β-azo)imidazole]platinum(II)

  摘要：

  1-Alkyl-2-(naphthyl-beta-azo)imidazoles (beta-NaiX, X=Me (3a),Et (3b), and CH2Ph (3c)) have been synthesized and reacted with K2PtCl4 in boiling MeCN-water ( 1:1, v/v) and Pt(beta-NaiX) Cl-2 (4) are isolated as orange-brown products. IR spectra support cis-PtCl2 configuration and the structural configuration has been carried out by the X-ray diffraction study of Pt(beta-NaiEt)Cl-2 (4b). The treatment of aqueous silver nitrate solution, followed by the addition of pyridine bases (Rpy) and NaClO4 to an acetonitrile solution of Pt(beta-NaiX)Cl-2 under boiling conditions has yielded [Pt(beta-NaiX)(Rpy)(2)] (ClO4)(2) (5-7). The structure has been established by spectroscopic data (IR, UV-Vis, H-1 NMR). The redox properties of the complexes exhibit azo reductions. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00385-5