| 1412334-06-5

• CAS: 1412334-06-5
• 化学式: C₆₄H₇₃FeNO₁₈
• 分子量: 1200.13
• InChiKey: KEAIVTOFJSDHKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 三氟乙酸 、 ammonium hexafluorophosphate 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 19.0h， 生成
  参考文献：
  名称：

  A Switchable Ferrocene-Based [1]Rotaxane with an Electrochemical Signal Output

  摘要：

  A [1]rotaxane, in which a linear rod is attached to one cyclopentadienyl (Cp) ring of a ferrocene unit and threaded into a dibenzo-24-crown-8 connected to the other Cp ring, was prepared. The mechanical motion of the rod-like part relative to the macrocycle has been demonstrated using H-1 NMR spectroscopy. Cyclic voltammetry (CV) showed that the system can be chemically switched between electrochemically reversible and irreversible states, depending on the inclusion and exclusion of the ammonium/amine group from the macrocycle.

  DOI：

  10.1021/ol302826g
• 作为产物：
  描述：

  1,1'-bisferrocenedicarboxylic acid 、 、 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 以39%的产率得到
  参考文献：
  名称：

  A Switchable Ferrocene-Based [1]Rotaxane with an Electrochemical Signal Output

  摘要：

  A [1]rotaxane, in which a linear rod is attached to one cyclopentadienyl (Cp) ring of a ferrocene unit and threaded into a dibenzo-24-crown-8 connected to the other Cp ring, was prepared. The mechanical motion of the rod-like part relative to the macrocycle has been demonstrated using H-1 NMR spectroscopy. Cyclic voltammetry (CV) showed that the system can be chemically switched between electrochemically reversible and irreversible states, depending on the inclusion and exclusion of the ammonium/amine group from the macrocycle.

  DOI：

  10.1021/ol302826g

文献信息

• Dual-Mode Operation of a Bistable [1]Rotaxane with a Fluorescence Signal
  作者：Hong Li、Ji-Na Zhang、Wei Zhou、Hui Zhang、Qiong Zhang、Da-Hui Qu、He Tian

  DOI：10.1021/ol401251u

  日期：2013.6.21

  We report the operation of a ferrocene-based bistable [1]rotaxane that can work in two parallel platforms. In an "active" signal mode, the relative mechanical movement of its ring and thread In response to external acid-base-stimuli can result in a remarkable fluorescence signal output observed by the naked eye, whereas no obvious fluorescence change occurred In a "silent" signal mode after oxidation. Its fluorescence responses to the different combinations of DBU and/or Fe(CIO4)(3) corresponds to an INHIBIT logic gate.