Rh((diphenylphosphino)pyridine)2(CO)Cl | 118301-76-1

• 英文名称: Rh((diphenylphosphino)pyridine)2(CO)Cl
• 英文别名: Rh(CO)Cl(2-(diphenylphosphino)pyridine)2
• CAS: 118301-76-1；118654-80-1；75361-60-3
• 化学式: C₃₅H₂₈ClN₂OP₂Rh
• 分子量: 692.926
• InChiKey: IPGRMIVQALQWMX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Rh((diphenylphosphino)pyridine)2(CO)Cl 、 di(rhodium)tetracarbonyl dichloride 以 二氯甲烷 为溶剂， 以78%的产率得到Rh2(μ-2-(diphenylphosphino)pyridine)2(μ-CO)Cl2
  参考文献：
  名称：

  Farr, James P.; Olmstead, Marilyn M.; Hunt, Catherine H., Inorganic Chemistry, 1981, vol. 20, # 4, p. 1182 - 1187

  摘要：

  DOI：
• 作为产物：
  描述：

  二苯基-2-吡啶膦 、 di(rhodium)tetracarbonyl dichloride 以 二氯甲烷 为溶剂， 以88%的产率得到Rh((diphenylphosphino)pyridine)2(CO)Cl
  参考文献：
  名称：

  2-(Diphenylphosphino)pyridine as a bridging ligand. Synthesis and structure of Rh2(Ph2Ppy)2(.mu.-CO)Cl2 and RhPd(Ph2Ppy)2(CO)Cl3

  摘要：

  DOI：

  10.1021/ja00541a088

文献信息

• Bimetallic Carbonyl Complexes Based on Iridium and Rhodium: Useful Tools for Hydrodefluorination Reactions
  作者：Konrad Kretschmar、Vladimir Pelmenschikov、Martin Kaupp、Thomas Braun、Philipp Wittwer、Simon Rachor、Jesvita Cardozo

  DOI：10.1002/ejic.202300099

  日期：——

  Various bimetallic carbonyl complexes based on iridium and rhodium were characterized and used in the catalytic hydrodefluorination of aryl C−F bonds with dihydrogen as reductant.

  表征了各种基于铱和铑的双金属羰基络合物，并将其用于以二氢作为还原剂的芳基 CF 键的催化加氢脱氟。
• Characterization and reactivity of some electrochemically generated products of Rh2(μ-dppp)2(μ-CO)Cl2 (dppp = 2-(diphenylphosphino)pyridine)
  作者：Clifton Woods、Louis J. Tortorelli

  DOI：10.1016/s0277-5387(00)80407-6

  日期：1988.1
• Farr, James P.; Olmstead, Marilyn M.; Balch, Alan L., Inorganic Chemistry, 1983, vol. 22, # 8, p. 1229 - 1235
  作者：Farr, James P.、Olmstead, Marilyn M.、Balch, Alan L.

  DOI：——

  日期：——
• Reaction of M(CO)Cl(L)2 with mercury(II) chloride (M=Ir, Rh; L=Ph2Ppy, P(fur)3) (Ph2Ppy=2-(diphenylphospino)pyridine, P(fur)3=tri-(2-furyl)phosphine)
  作者：Shan-Ming Kuang、Feng Xue、Thomas C.W. Mak、Zheng-Zhi Zhang

  DOI：10.1016/s0020-1693(98)00272-2

  日期：1999.1

  Reaction of Ir(CO)Cl(Ph(2)Ppy)(2) with mercury(II) chloride gave Ir(CO)Cl-2(mu-Ph(2)Ppy)(2)HgCl (1), as the main product and Ir-2(CO)(2)Cl-4(mu-Ph(2)Ppy)(2) (2), as the by-product, whereas reaction of Ir(CO)ClP(fur)(3)}(2) with mercury(II) chloride only gave Ir(CO)Cl-2P(fur)(3)}(2)HgCl (3). Reaction of Rh(CO)Cl(L)(2) with mercury(II) chloride gave Rh(CO)Cl-2(mu-L)(2)HgCl (L = Ph(2)Ppy (4); L = P(fur)(3) (5)). The crystal and molecular structures of 2 . CH2Cl2, 4.1/2H(2)O and 5 have been determined by X-ray analysis. (C) 1999 Elsevier Science S.A. All rights reserved.