(thiazolidin-2-ylidene-l4-sulfaneyl)bis(triphenyl-l5-arsaneyl)copper(IV) bromide | 168977-45-5

• 英文名称: (thiazolidin-2-ylidene-l4-sulfaneyl)bis(triphenyl-l5-arsaneyl)copper(IV) bromide
• CAS: 168977-45-5
• 化学式: C₃₉H₃₅As₂BrCuNS₂
• 分子量: 875.139
• InChiKey: VMJKEIIMSZQVMH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-巯基噻唑啉 、 三苯胂 、 copper(I) bromide 以 苯 为溶剂， 以66%的产率得到(thiazolidin-2-ylidene-l4-sulfaneyl)bis(triphenyl-l5-arsaneyl)copper(IV) bromide
  参考文献：
  名称：

  Synthesis and characterization of mixed ligand copper(I) complexes containing halides, triphenylarsine and N,N-dimethyl-N′-phenylthiourea (dmptH), N,N-dibutyl-N′-phenylthiourea (dbptH) or 1,3-thiazolidine-2-thione (tzdtH). The X-ray crystal structure of [Cu(PPh3)2(dmptH)Cl]

  摘要：

  The arsine complexes [Cu(AsPh(3))(2)(LH)X] (LH = N,N-dimethyl-N'-phenylthiourea (dmptH), N,N-dibutyl-N'-phenylthiourea (dbptH) or 1,3-thiazolidine-2-thione (tzdtH); X = Cl, Br, I) have been prepared and characterized on the basis of analytical, IR, electronic (UV-vis), H-1 NMR, conductivity and magnetic measurements. In all cases there is a distorted tetrahedral environment around copper(I) and the ligands (LH) bind through thione sulphur atom to copper(I). We also report the crystal structure of complex [Cu(PPh(3))(2)(dmptH)Cl] which shows that metal ion has a distorted tetrahedral geometry with bond lengths Cu-S=2.459(2), Cu-Cl=2.308(1), Cu-P(1)=2.305(1) and Cu-P(2) = 2.313(1) Angstrom. The NH is intramolecularly hydrogen bonded to Cl with a bond distance NH ... Cl = 2.31 Angstrom.

  DOI：

  10.1016/0277-5387(94)00478-w