[(TiCl)2(μ-O)(SiMe2)2(η(5)-C5H3)2]2(μ-O)2 | 215375-10-3

• 英文名称: [(TiCl)2(μ-O)(SiMe2)2(η(5)-C5H3)2]2(μ-O)2
• CAS: 215375-10-3；215321-14-5
• 化学式: C₂₈H₃₆Cl₄O₄Si₄Ti₄
• 分子量: 882.265
• InChiKey: BVDVDHSJSRPCGW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-[(TiCl3)2(SiMe2)2(η(5)-C5H3)2] 、 水 以 氘代苯 为溶剂， 生成 [(TiCl)2(μ-O)(SiMe2)2(η(5)-C5H3)2]2(μ-O)2
  参考文献：
  名称：

  Cis- and trans-titanium complexes with doubly silyl-bridged dicyclopentadienyl ligands: molecular structure of [(TiCl)2(μ-O){(SiMe2)2(η5-C5H3)2}]2(μ-O)2

  摘要：

  The reaction of TiCl4 with Li-2[(SiMe2)(2)(n(5)-C5H3)(2)] in toluene at room temperature afforded a mixture of cis- and trans- [(TiCl3)(2){(SiMe2)(2)(eta(5)-C5H3)(2)}] in a molar ratio of 1/2 after recrystallization. The complex trans-[(TiCl3)(2){(SiMe2)(2)(eta(5)-C5H3)(2)}] was hydrolyzed immediately by the addition of water to THF solutions to give trans-[(TiCl2)(2)(mu-O){(SiMe2)(2)(eta(5)-C5H3)(2)}] as a solid insoluble in all organic solvents, whereas hydrolysis of cis-[(TiCl3)(2){(SiMe2)(2)(eta(5)-C5H3)2}] under different conditions led to the dinuclear mu-oxo complex cis-[(TiCl2)(2)(mu-O) {(SiMe2)(2)(eta(5)-C5H3)(2)}] and two oxo complexes of the same stoichiometry [(TiCl)(2)(mu-O){(SiMe2)(2)(eta(5)-C5H3)(2)}](2)(mu-O)(2) as crystalline solids. Alkylation of cis- and trans-[(TiCl3)(2){(SiMe2)(2)(mu(5)-C5H3)(2)}] With MgClMe led respectively to the partially alkylated cis-[(TiMe2Cl)(2){(SiMe2)(2)(eta(5)-C5H3)(2)}] and the totally alkylated trans-[(TiMe3)(2){(SiMe2)(2)(eta(5)-C5H3)(2)}] compounds. The crystal and molecular structure of the tetranuclear oxo complex [(TiCl)(2)(mu-O){(SiMe2)(2)(eta(5)-C5H3)(2)}](2)(mu-O)(2) was determined by X-ray diffraction. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00170-4