(η(5)-2,4-cyclopentadien-1-yl)(di-t-butyl (η(6)-phenyl)imino-3,3'-dipropanoate)ruthenium hexafluorophosphate | 174499-45-7

• 英文名称: (η(5)-2,4-cyclopentadien-1-yl)(di-t-butyl (η(6)-phenyl)imino-3,3'-dipropanoate)ruthenium hexafluorophosphate
• CAS: 174499-45-7
• 化学式: C₂₅H₃₆NO₄Ru*F₆P
• 分子量: 660.599
• InChiKey: WVQDWOLQUDMJBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate 、 di-t-butyl phenylimino-3,3'-dipropanoate 以 二氯甲烷 为溶剂， 以71%的产率得到(η(5)-2,4-cyclopentadien-1-yl)(di-t-butyl (η(6)-phenyl)imino-3,3'-dipropanoate)ruthenium hexafluorophosphate
  参考文献：
  名称：

  Towards the synthesis of amino[b,e][1,4]dioxin derivatives via cationic ruthenium complexes

  摘要：

  Double nucleophilic aromatic substitution reactions between N-substituted (eta(6)-1,2-dichlorobenzene)RuCp(+) salts and substituted 1,2-benzenediols have been carried out under mild conditions to prepare N-substituted (eta(6)-dibenzo[b,e][1,4]dioxin)ruthenium(II) complexes. The dibenzodioxin ligands were subsequently liberated by photolysis, with radiation from a sunlamp or from a medium pressure Hg lamp (300 nm).

  DOI：

  10.1016/0022-328x(95)05717-4