[Ag(μ-ONO2)(2-aminopyridine)(AsPh3)2]2 | 1211466-24-8

• 英文名称: [Ag(μ-ONO2)(2-aminopyridine)(AsPh3)2]2
• CAS: 1211466-24-8
• 化学式: C₄₆H₄₂Ag₂As₂N₆O₆
• 分子量: 1140.46
• InChiKey: JTTYWORWNOCWKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 三苯胂 、 silver nitrate 以 甲醇 、 二氯甲烷 为溶剂， 以74%的产率得到[Ag(μ-ONO2)(2-aminopyridine)(AsPh3)2]2
  参考文献：
  名称：

  Synthesis and structural characterisation of five copper(I) and silver(I) complexes with 2-aminopyridine (2-APy), [Cu(μ-Cl)(2-Apy)(PPh3)]2, [Ag(μ-X)(2-Apy)(PPh3)]2 (X=Cl, Br), [Ag(μ-ONO2)(2-Apy)(EPh3)]2 (E=P, As)

  摘要：

  Five new copper(I)/silver(I) complexes containing 2-aminopyridine, [Cu(mu-Cl)(2-Apy)(PPh3)](2) (1), [Ag(mu-Cl)(2-Apy)(PPh3)](2)(2), [Ag(mu-Br)(2-Apy)PPh3)](2)(3), [Ag(mu-ONO2)(2-Apy)(PPh3)](2)(4), [Ag(mu-ONO2)(2-Apy)(AsPh3)](2)(5) have been synthesised for the first time. Complexes 1-5 are obtained by the reactions of MX (MX = CuCl for 1: M = Ag for 2-5: X = Cl, Br for 2-3; X = NO3 for 4-5) with the monodentate ligands EPh3 (E = P for 1-4: E = As for 5) and 2-Apy in the molar ratio of 1: 1:2 in the mixed solvent of CH2Cl2 and MeOH. Complexes 1-5 are characterised by IR and X-ray diffraction. In 1-5, chloride, bromide and nitrate ions bridge two metal atoms to form dinuclear complexes containing the parallelogram cores M2X2 (M = Cu, Ag). (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.036