{(Mo(CO)4(P(OMe)3))2(μ-{PhNP(OCH2CF3)}2)} | 145086-16-4

• 英文名称: {(Mo(CO)4(P(OMe)3))2(μ-{PhNP(OCH2CF3)}2)}
• CAS: 145086-16-4
• 化学式: C₃₀H₃₂F₆Mo₂N₂O₁₆P₄
• 分子量: 1106.35
• InChiKey: WKAZLZALGGDTPB-XDVBQSPXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-{molybdenum(0)(carbonyl)4(piperidine)(P(O-methyl)3)} 、 trans-{PhNP(OCH2CF3)}2 以 二氯甲烷 为溶剂， 以65%的产率得到{(Mo(CO)4(P(OMe)3))2(μ-{PhNP(OCH2CF3)}2)}
  参考文献：
  名称：

  Organometallics of diphosphazanes

  摘要：

  The reactions of cyclodiphosphazanes [PhNP(OR)]2 (R = CH2CF3 (1) and C6H4Me-p (2)) with Group 6 metal carbonyl derivatives have been investigated. The stereochemistry of the ligand appears to play a significant role in determining its coordination behaviour. The cyclodiphosphazane 1 (isolated as the trans-isomer) affords the dinuclear complexes 9-11 in which the two metal centres are bridged by the diphosphazane ligand. In contrast the cyclodiphosphazane 2 (isolated as a 3/1 mixture of cis- and trans-isomers) yields the mononuclear complexes 3-7 in which the cyclodiphosphazane is coordinated in the eta1-fashion. The structures of [W(CO4(NHC5H10){(PhNP(OC6H4Me-p))2}] (6) and [{Mo(CO)4(NHC5H10)}2{mu-[PhNP(OCH2CF3)]2}] (9a) have been determined by X-ray crystallography.

  DOI：

  10.1016/0022-328x(92)88010-g

文献信息

• Krishnamurthy, S. S.; Reddy, V. Sreenivasa; Chandrasekaran, A., Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 64, # 1-4, p. 99 - 106
  作者：Krishnamurthy, S. S.、Reddy, V. Sreenivasa、Chandrasekaran, A.、Nethaji, M.

  DOI：——

  日期：——