trans-[(κ3-diacetylpyridinemonooxime)Ru(Cl)(PPh3)2] | 1084810-98-9

• 英文名称: trans-[(κ3-diacetylpyridinemonooxime)Ru(Cl)(PPh3)2]
• CAS: 1084810-98-9
• 化学式: C₄₅H₃₉ClN₂O₂P₂Ru
• 分子量: 838.287
• InChiKey: HYYZGAZIKDKFCY-ZNHJFZBDSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trans-[(κ3-diacetylpyridinemonooxime)Ru(Cl)(PPh3)2]PF6 在 NaBH₄ 作用下， 以 二乙二醇二甲醚 、 水 、 乙腈 为溶剂， 以69%的产率得到trans-[(κ3-diacetylpyridinemonooxime)Ru(Cl)(PPh3)2]
  参考文献：
  名称：

  Reactivity of the Oxime/Oximato Group in Ruthenium(II) Complexes

  摘要：

  Oxime targeted reactions of the complexes trans-[(kappa(3)-dapdOH)Ru(CO)(PPh3)(2)]PF6 (1) (dapdOH = diacetylpyridinedioxime) and trans-[(kappa(3)-dapmOH)RuCl(PPh3)(2)]PF6 (2) (dapmOH = diacetylpyridinemonooxime) with SOCl2, NaBH4, or HCHO led into conversion of oxime to oximato, imino, or hydroxymethylimino groups. The reaction products have been characterized by analytical and spectral studies. Molecular structures of the representative homo/heteroleptic oxime/oximato complexes trans-[(kappa(3)-dapdOH)Ru(CO)(Pph(3))(2)]PF6 (1), trans-[(kappa(3)-dapdO)Ru(CO)(PPh3)(2)] (11) and oximato/imino complex trans-[(kappa(3)-dapd-NH)Ru(CO)(PPh3)(2)]PF6 (13) have been authenticated by single-crystal X-ray diffraction analyses. Structural studies revealed the presence of various oxime/oximato/ imino based O-H center dot center dot center dot O, C-H center dot center dot center dot O, and N-H center dot center dot center dot F interactions in the complexes 1, 11, and 13.

  DOI：

  10.1021/ic8009699